The crucial role of CO as a ligand in the formation of long-lived neutral iron complexes in the gas phase

被引：12

作者：

Schröder, D ^{[1
]}

Bärsch, S ^{[1
]}

Schwarz, H ^{[1
]}

机构：

[1] Tech Univ Berlin, Inst Organ Chem, D-10623 Berlin, Germany

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 309卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(99)00703-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Neutralization reionization (NR) mass spectra of mono- and bis-ligated iron cations Fe(L)(n)(+) (n = 1, 2) are reported for the simple ligands L = H2O, CO, C2H4, C4H6, C6H6, and NH3. Most of these iron complexes do not survive the NR process, and dissociation of the neutrals into Fe(+)nL prevails. Interestingly, those complexes containing CO ligands exhibit much more pronounced recovery signals in the NR spectra. Electronic arguments imply that the carbonyl ligand favors the generation of low-spin complexes of neutral iron which are less prone to dissociate and are not accessed with the other Ligands. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：407 / 413

页数：7

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