Control of polymer structure by chain transfer processes

被引：23

作者：

Rizzardo, E

Chong, YK

Evans, RA

Moad, G

Thang, SH

机构：

来源：

MACROMOLECULAR SYMPOSIA | 1996年 / 111卷

关键词：

D O I：

10.1002/masy.19961110103

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Chain transfer can be performed effectively by a mechanism of addition-fragmentation with appropriately substituted allylic compounds, vinyl ethers and thionoesters. Selection of substituents allows the optimization of chain transfer activity and the preparation of macromonomers and other end-functional polymers from acrylates, methacrylates, styrene and vinyl acetate. The addition-fragmentation concept has been extended to the free radical ring-opening polymerization of cyclic allylic sulfides.

引用

页码：1 / 11

页数：11

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