Top-down fabrication of three-dimensional porous V2O5 hierarchical microplates with tunable porosity for improved lithium battery performance

被引:76
作者
An, Qinyou [1 ]
Zhang, Pengfei [1 ]
Wei, Qiulong [1 ]
He, Liang [1 ]
Xiong, Fangyu [1 ]
Sheng, Jinzhi [1 ]
Wang, Qinqin [1 ]
Mai, Liqiang [1 ]
机构
[1] Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, WUT Harvard Joint Nano Key Lab, Wuhan 430070, Peoples R China
基金
中国国家自然科学基金;
关键词
TEMPLATE-FREE SYNTHESIS; CATHODE MATERIAL; ION BATTERY; HOLLOW MICROSPHERES; NANOSTRUCTURED MATERIALS; ENERGY-CONVERSION; RATE CAPABILITY; ANODE MATERIALS; STORAGE; NANOWIRES;
D O I
10.1039/c3ta14818a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Three-dimensional porous V2O5 hierarchical microplates have been fabricated by a one-step top-down strategy, and display an excellent rate capability and stable capacity of 110 mA h g(-1) at 2000 mA g(-1) after 100 cycles. We have demonstrated that the facile approach of a solid-phase conversion is promising for large-scale fabrication of highly porous micro/nano materials.
引用
收藏
页码:3297 / 3302
页数:6
相关论文
共 61 条
[1]   Supercritically exfoliated ultrathin vanadium pentoxide nanosheets with high rate capability for lithium batteries [J].
An, Qinyou ;
Wei, Qiulong ;
Mai, Liqiang ;
Fei, Jiayang ;
Xu, Xu ;
Zhao, Yunlong ;
Yan, Mengyu ;
Zhang, Pengfei ;
Huang, Shizhe .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2013, 15 (39) :16828-16833
[2]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[3]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[4]   Synthesis of layered LiMnO2 as an electrode for rechargeable lithium batteries [J].
Armstrong, AR ;
Bruce, PG .
NATURE, 1996, 381 (6582) :499-500
[5]   Electrospun nano-vanadium pentoxide cathode [J].
Ban, Chunmei ;
Chernova, Natalya A. ;
Whittingham, M. Stanley .
ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (03) :522-525
[6]   Self-assembled vanadium pentoxide (V2O5) hollow microspheres from nanorods and their application in lithium-ion batteries [J].
Cao, AM ;
Hu, JS ;
Liang, HP ;
Wan, LJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (28) :4391-4395
[7]   High-performance lithium battery anodes using silicon nanowires [J].
Chan, Candace K. ;
Peng, Hailin ;
Liu, Gao ;
McIlwrath, Kevin ;
Zhang, Xiao Feng ;
Huggins, Robert A. ;
Cui, Yi .
NATURE NANOTECHNOLOGY, 2008, 3 (01) :31-35
[8]   Fast, completely reversible Li insertion in vanadium pentoxide nanoribbons [J].
Chan, Candace K. ;
Peng, Hailin ;
Twesten, Ray D. ;
Jarausch, Konrad ;
Zhang, Xiao Feng ;
Cui, Yi .
NANO LETTERS, 2007, 7 (02) :490-495
[9]   Reversible Lithium-Ion Storage in Silver-Treated Nanoscale Hollow Porous Silicon Particles [J].
Chen, Dongyun ;
Mei, Xiao ;
Ji, Ge ;
Lu, Meihua ;
Xie, Jianping ;
Lu, Jianmei ;
Lee, Jim Yang .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (10) :2409-2413
[10]   3D heterostructured architectures of Co3O4 nanoparticles deposited on porous graphene surfaces for high performance of lithium ion batteries [J].
Choi, Bong Gill ;
Chang, Sung-Jin ;
Lee, Young Boo ;
Bae, Jong Seong ;
Kim, Hae Jin ;
Huh, Yun Suk .
NANOSCALE, 2012, 4 (19) :5924-5930