Formamides undergo in-plane bimolecular nucleophilic vinylic substitutions (SN2) by the reaction with (E)-alkenyl(phenyl)iodonium tetrafluoroborates:: stereoselective synthesis of (Z)-vinyl formates

被引：24

作者：

Ochiai, M ^{[1
]}

Yamamoto, S ^{[1
]}

Sato, K ^{[1
]}

机构：

[1] Univ Tokushima, Fac Pharmaceut Sci, Tokushima 7708505, Japan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 15期

关键词：

D O I：

10.1039/a904220b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reported for the first time is the stereoselective synthesis of (Z)-vinyl formates, which involves in-plane bimolecular nucleophilic vinylic substitutions of (E)-beta-alkylvinyl(phenyl)iodonium tetrafluoroborates with formamides.

引用

页码：1363 / 1364

页数：2

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