Trimethylsilyl bis(fluorosulfonyl)imide: An efficient catalyst for the addition of trimethylsilyl cyanide to carbonyl compounds

被引：13

作者：

Kaur, H ^{[1
]}

Kaur, G ^{[1
]}

Trehan, S ^{[1
]}

机构：

[1] PANJAB UNIV, DEPT CHEM, CHANDIGARH 160014, INDIA

来源：

SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 10期

关键词：

D O I：

10.1080/00397919608003546

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of 1 mol% of trimethylsilyl bis(fluorosulfonyl)imide, trimethylsilyl cyanide adds efficiently to carbonyl compounds. The catalyst has been found to be more active than trimethylsilyl triflate for the above reaction.

引用

页码：1925 / 1929

页数：5

共 8 条

[1]

Colvin E. W., 1988, SILICON REAGENTS ORG

[2]

Colvin E. W., 1981, SILICON ORGANIC SYNT, P165

[3]

EMDE H, 1982, SYNTHESIS-STUTTGART, P1

[4] TRIMETHYLSILYL TRIFLATE CATALYZED ALDOL-TYPE REACTION OF ENOL SILYL ETHERS AND ACETALS OR RELATED-COMPOUNDS [J].

MURATA, S ;

SUZUKI, M ;

NOYORI, R .

TETRAHEDRON, 1988, 44 (13) :4259-4275

[5] TRIMETHYSILYL TRIFLATE IN ORGANIC-SYNTHESIS .11. [J].

NOYORI, R ;

MURATA, S ;

SUZUKI, M .

TETRAHEDRON, 1981, 37 (23) :3899-3910

[6] N-FLUOROPERFLUOROALKYLSULFONIMIDES - REMARKABLE NEW FLUORINATION REAGENTS [J].

SINGH, S ;

DESMARTEAU, DD ;

ZUBERI, SS ;

WITZ, M ;

HUANG, HN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (23) :7194-7196

[7] TRIMETHYLSILYL BIS(FLUOROSULFONYL)IMIDE - A NEW CATALYST FOR THE REACTIONS OF ACETALS WITH SILYL NUCLEOPHILES [J].

TREHAN, A ;

VIJ, A ;

WALIA, M ;

KAUR, G ;

VERMA, RD ;

TREHAN, S .

TETRAHEDRON LETTERS, 1993, 34 (45) :7335-7338

[8]

Weber W. P., 1983, SILICON REAGENTS ORG

← 1 →