Synthesis of functionalized fullerene by mono-alkylation of fullerene cyclopentadienide

被引:32
作者
Hamasaki, R [1 ]
Matsuo, Y [1 ]
Nakamura, E [1 ]
机构
[1] Univ Tokyo, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan
关键词
D O I
10.1246/cl.2004.328
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Mono-alkylation reaction of a fullerene cyclopentadienide with a functionalized alkyl halide quantitatively gave a functionalized [60]fullerene derivative that may bear a variety of functional groups and may exhibit high solubility in various solvents.
引用
收藏
页码:328 / 329
页数:2
相关论文
共 19 条
[1]   Double-cable polymers for fullerene based organic optoelectronic applications [J].
Cravino, A ;
Sariciftci, NS .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (07) :1931-1943
[2]   Endohedral homoconjugation in cyclopentadiene embedded in C60. Theoretical and electrochemical evidence [J].
Iikura, H ;
Mori, S ;
Sawamura, M ;
Nakamura, E .
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (23) :7912-7913
[3]   Synthesis of fullerene glycoconjugates through sulfide connection in aqueous media [J].
Isobe, H ;
Mashima, H ;
Yorimitsu, H ;
Nakamura, E .
ORGANIC LETTERS, 2003, 5 (23) :4461-4463
[4]   One-step multiple addition of amine to [60]fullerene. - Synthesis of tetra(amino)fullerene epoxide under photochemical aerobic conditions [J].
Isobe, H ;
Tomita, N ;
Nakamura, E .
ORGANIC LETTERS, 2000, 2 (23) :3663-3665
[5]   Stacking of molecules possessing a fullerene apex and a cup-shaped cavity connected by a silicon connection [J].
Matsuo, Y ;
Muramatsu, A ;
Hamasaki, R ;
Mizoshita, N ;
Kato, T ;
Nakamura, E .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (02) :432-433
[6]   Theoretical studies on structures and aromaticity of finite-length armchair carbon nanotubes [J].
Matsuo, Y ;
Tahara, K ;
Nakamura, E .
ORGANIC LETTERS, 2003, 5 (18) :3181-3184
[7]   Chemistry of η5-fullerene metal complexes [J].
Nakamura, E ;
Sawamura, M .
PURE AND APPLIED CHEMISTRY, 2001, 73 (02) :355-359
[8]   Functionalized fullerenes in water. The first 10 years of their chemistry, biology, and nanoscience [J].
Nakamura, E ;
Isobe, H .
ACCOUNTS OF CHEMICAL RESEARCH, 2003, 36 (11) :807-815
[9]   Synthesis, structure, and aromaticity of a hoop-shaped cyclic benzenoid [10]cyclophenacene [J].
Nakamura, E ;
Tahara, K ;
Matsuo, Y ;
Sawamura, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (10) :2834-2835
[10]   SOLUBILITY OF C-60 IN A VARIETY OF SOLVENTS [J].
RUOFF, RS ;
TSE, DS ;
MALHOTRA, R ;
LORENTS, DC .
JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (13) :3379-3383