Liquid deposition of hydrogenated carbon films in N,N-dimethyl formamide solution

被引：13

作者：

Jiu, JT ^{[1
]}

Cai, K ^{[1
]}

Fu, Q ^{[1
]}

Cao, CB ^{[1
]}

Zhu, HS ^{[1
]}

机构：

[1] Beijing Inst Technol, Res Ctr Mat Sci, Beijing 100081, Peoples R China

来源：

MATERIALS LETTERS | 1999年 / 41卷 / 02期

基金：

中国国家自然科学基金;

关键词：

diamond-like film; liquid phase electrodeposition; Raman spectroscopy;

D O I：

10.1016/S0167-577X(99)00104-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Using a pulse-modulated source, an attempt has been made to deposit diamond-like carbon films by electrodeposition in N,N-dimethyl formamide (DMF) solution. XPS showed the films mainly contain carbon. IR spectrum indicated that as-deposited films are hydrogenated carbon films, and Che hydrogen mainly bonded to sp(3) carbon. Raman spectroscopy suggested that the films contained a mixture of sp(3) and sp(2) carbon. For the first time, we obtained Raman scattering at 1337 cm(-1), which is very close to the characteristic Raman line of diamond located at 1332 cm(-1) except for the large linewidth. The electrical resistivity of the films is more than 10(10) Omega cm. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：63 / 66

页数：4

共 17 条

[1] MODELING STUDIES OF AMORPHOUS-CARBON [J].

BEEMAN, D ;

SILVERMAN, J ;

LYNDS, R ;

ANDERSON, MR .

PHYSICAL REVIEW B, 1984, 30 (02) :870-875

[2]

BOU P, 1991, J ELECTROCHEM SOC, V138, P2291

[3]

Colthup N.B., 1990, INTRO IR RAMAN SPECT

[4] USE OF RAMAN-SCATTERING TO INVESTIGATE DISORDER AND CRYSTALLITE FORMATION IN AS-DEPOSITED AND ANNEALED CARBON-FILMS [J].

DILLON, RO ;

WOOLLAM, JA ;

KATKANANT, V .

PHYSICAL REVIEW B, 1984, 29 (06) :3482-3489

[5] BONDING IN HYDROGENATED HARD CARBON STUDIED BY OPTICAL SPECTROSCOPY [J].

DISCHLER, B ;

BUBENZER, A ;

KOIDL, P .

SOLID STATE COMMUNICATIONS, 1983, 48 (02) :105-108

[6] Characterization of cathodically deposited carbonaceous films on a silicon substrate [J].

Kwiatek, SE ;

Desai, V ;

Moran, PJ ;

Natishan, PM .

JOURNAL OF MATERIALS SCIENCE, 1997, 32 (12) :3123-3128

[7] SIDEBANDS IN THE LUMINESCENCE SPECTRA OF AMORPHOUS HYDROGENATED CARBON [J].

LIN, S ;

FELDMAN, BJ .

PHYSICAL REVIEW LETTERS, 1982, 48 (12) :829-831

[8] ANALYSIS OF THE STRUCTURE OF MULTICOMPONENT CARBON-FILMS BY RESONANT RAMAN-SCATTERING [J].

MARCUS, B ;

FAYETTE, L ;

MERMOUX, M ;

ABELLO, L ;

LUCAZEAU, G .

JOURNAL OF APPLIED PHYSICS, 1994, 76 (06) :3463-3470

[9] Some unusual features in the Raman spectrum of amorphous-carbon films obtained by pyrolysis of maleic anhydride [J].

Subramanyam, SV ;

Sayeed, A ;

Meenakshi, V ;

Bhattacharya, S ;

Cholli, A ;

Tripathi, S .

JOURNAL OF APPLIED PHYSICS, 1997, 81 (06) :2907-2909

[10] DEPOSITION OF CARBON-FILMS BY ELECTROLYSIS OF A WATER-ETHYLENE GLYCOL SOLUTION [J].

SUZUKI, T ;

MANITA, Y ;

YAMAZAKI, T ;

WADA, S ;

NOMA, T .

JOURNAL OF MATERIALS SCIENCE, 1995, 30 (08) :2067-2069

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