Copper(I) salt promoted homo-coupling reaction of organosilanes

被引:103
作者
Ikegashira, K [1 ]
Nishihara, Y [1 ]
Hirabayashi, K [1 ]
Mori, A [1 ]
Hiyama, T [1 ]
机构
[1] TOKYO INST TECHNOL, RESOURCES UTILIZAT RES LAB, MIDORI KU, YOKOHAMA, KANAGAWA 226, JAPAN
关键词
D O I
10.1039/a701898c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Alkenylfluorosilanes, phenylfluorosilanes or alkynylsilanes smoothly dimerize in the presence of a copper(I) salt in a polar solvent such as N,N-dimethylformamide (DMF) or dimethyl sulfoxide (DMSO) to give the 1,3-conjugated dienes, biphenyl or 1,3-conjugated diynes, respectively.
引用
收藏
页码:1039 / 1040
页数:2
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