Stoichiometric alkane dehydrogenation with Tp′PtMe2H to form Tp′Pt(η2-olefin)(H) complexes

被引：29

作者：

Kostelansky, Cynthia Norris ^{[1
]}

MacDonald, Margaret G. ^{[1
]}

White, Peter S. ^{[1
]}

Templeton, Joseph L. ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

ORGANOMETALLICS | 2006年 / 25卷 / 12期

关键词：

D O I：

10.1021/om0510829

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Gentle heating of Tp'PtMe2H (1) in alkane solvents in the presence of B(C6F5)(3) results in C-H activation of the alkane solvent, R-H, to give Tp'Pt(Me)(H)(R) intermediates. Further heating leads to formation of Tp'Pt(eta(2)-olefin)(H) complexes via methane elimination followed by beta-hydride elimination, a stoichiometric alkane to olefin conversion.

引用

页码：2993 / 2998

页数：6

共 51 条

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