Metal-ion control of molecular recognition-sugar-functionalised 2,2′:6′,2"-terpyridines

被引：27

作者：

Constable, EC ^{[1
]}

Mundwiler, S ^{[1
]}

机构：

[1] Inst Inorgan Chem, CH-4056 Basel, Switzerland

来源：

POLYHEDRON | 1999年 / 18卷 / 18期

关键词：

ligands; 2,2 ': 6 ',2 ''-terpyridine; sugar; iron; ruthenium; supramolecular chemistry;

D O I：

10.1016/S0277-5387(99)00134-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new class of ligands in which a sugar is covalently linked to a 2,2':6',2 "-terpyridine metal-binding domain has been prepared. Iron(II) and ruthenium(II) complexes have been prepared and strategies involving deprotection of coordinated ligands have been developed. The metal complexes do not undergo enzymatic reactions characteristic of the sugar substituents, even though the free ligands do. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：2433 / 2444

页数：12

共 14 条

[1]

COLLINS P, 1995, MONOSACCHARIDES

[2] Hydrogen-bond recognition of nucleosides by oligopyridine ligands and their ruthenium complexes [J].