Synthesis and structures of the novel manganese(-I) fullerene-[60] complexes M[Mn(CO)4(η2-C60)] (M = Na, PPN)

被引：22

作者：

Bengough, MN

Thompson, DM

Baird, MC ^{[1
]}

Enright, GD

机构：

[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada

[2] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R9, Canada

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 16期

关键词：

D O I：

10.1021/om990361r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The thermal and photochemical reactions of M[Mn(CO)(5)] (M = Na, PPN) with C-60 and the photochemical reaction of Mn-2(CO)(10) with M[C-60] give the same green complex of Mn(-I), M[Mn(CO)(4)(eta(2)-C-60)]. The C-60 coordinates conventionally via a six-six ring junction but appears to be a better pi-acceptor than. CO, since the average of the carbonyl stretching frequencies of PPN[Mn(CO)(4)(eta(2)C(60))] is similar to 77 cm(-1) higher than the average of those of PPN[Mn(CO)(5)].

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页码：2950 / 2952

页数：3

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