Highly active and selective catalysts for the production of methyl propanoate via the methoxycarbonylation of ethene

被引:233
作者
Clegg, W
Eastham, GR
Elsegood, MRJ
Tooze, RP
Wang, XL
Whiston, K
机构
[1] ICI Acryl, Strateg Projects Grp, Middlesbrough TS90 8JE, Cleveland, England
[2] Newcastle Univ, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
[3] Univ Durham, Dept Chem, Sci Labs, Durham DH1 3LE, England
关键词
D O I
10.1039/a905521e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A highly active and selective catalyst for the production of methyl propanoate via the methoxycarbonylation of ethene is described, based on the new zero valent palladium complex L2Pd(dba) [where L-2 = 1,2-bis(di-tert-butylphosphinomethyl)benzene and dba = trans,trans-dibenzylideneacetone].
引用
收藏
页码:1877 / 1878
页数:2
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