Palladium-catalyzed convergent synthesis and properties of conjugated dendrimers based on triarylethene branching

被引：61

作者：

Itami, K ^{[1
]}

Tonogaki, K

Nokami, T

Ohashi, Y

Yoshida, J

机构：

[1] Nagoya Univ, Res Ctr Mat Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[2] Japan Sci & Technol Agcy JST, PRESTO, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[3] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 15期

关键词：

C-C coupling; dendrimers; fluorescence; homogeneous catalysis; palladium;

D O I：

10.1002/anie.200600063

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Branching out: Pd-catalyzed iterative triarylations of vinylboronate afford conjugated dendrimers with triarylethene branches (see picture) in a flexible and convergent manner. These highly branched dendrimers reveal good solubility in common organic solvents and exhibit high quantum yields of fluorescence, with the color of the emission ranging from blue to red depending on the extent of branching and hence π conjugation. (Figure Presented) © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2404 / 2409

页数：6

共 55 条

[1] The heck reaction as a sharpening stone of palladium catalysis [J].

Beletskaya, IP ;

Cheprakov, AV .

CHEMICAL REVIEWS, 2000, 100 (08) :3009-3066

[2]

Brase S., 2002, HDB ORGANOPALLADIUM, DOI 10.1002/0471212466

[3] Synthesis, characterization and optical response of polyene-cored stilbenoid dendrimers [J].

Cano-Marín, AR ;

Díez-Barra, E ;

Rodríguez-López, J .

TETRAHEDRON, 2005, 61 (02) :395-400

[4] Giant extended π-conjugated dendrimers containing the 10,15-dihydro-5H-diindeno[1,2-α;1′,2′-c]fluorene chromophore:: Synthesis, NMR behaviors, optical properties, and electroluminescence [J].

Cao, XY ;

Liu, XH ;

Zhou, XH ;

Zhang, Y ;

Jiang, Y ;

Cao, Y ;

Cui, YX ;

Pei, J .

JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (18) :6050-6058

[5] FINE FEATHERS MAKE FINE BIRDS - THE HECK REACTION IN MODERN GARB [J].

DE MEIJERE, A ;

MEYER, FE .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1994, 33 (23-24) :2379-2411

[6]

de Meijere A, 1994, ANGEW CHEM, V106, P2473, DOI DOI 10.1002/ANGE.19941062307

[7] A simple orthogonal approach to poly(phenylenevinylene) dendrimers [J].

Deb, SK ;

Maddux, TM ;

Yu, LP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (38) :9079-9080

[8] Synthesis, characterization, and optical response of dipolar and non-dipolar poly(phenylenevinylene) dendrimers [J].

Díez-Barra, E ;

García-Martínez, JC ;

Merino, S ;

del Rey, R ;

Rodríguez-López, J ;

Sánchez-Verdú, P ;

Tejeda, J .

JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (17) :5664-5670

[9] Synthesis of new 1,1′-binaphthyl-based chiral phenylenevinylene dendrimers [J].

Díez-Barra, E ;

García-Martínez, JC ;

Rodríguez-López, J ;

Gómez, R ;

Segura, JL ;

Martín, N .

ORGANIC LETTERS, 2000, 2 (23) :3651-3653

[10] Convergent dendrons and dendrimers:: from synthesis to applications [J].

Grayson, SM ;

Fréchet, JMJ .

CHEMICAL REVIEWS, 2001, 101 (12) :3819-3867

← 1 2 3 4 5 6 →