[2+2+2] cyclotrimerisation of bisaryl acetylene bearing ferrocenyl units with planar chirality: synthesis of enantiopure conjugated polyferrocene complexes

被引：18

作者：

Mamane, V ^{[1
]}

Gref, A ^{[1
]}

Lefloch, F ^{[1
]}

Riant, O ^{[1
]}

机构：

[1] Univ Paris 11, ICMO, Lab Catalyse Mol, F-91405 Orsay, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 637卷

关键词：

ferrocenyl complexes; planar chirality; cyclic voltametry; cyclotrimerisation;

D O I：

10.1016/S0022-328X(01)00945-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new family of highly symmetric and fully conjugated hexaferrocenyl complexes were prepared by a [2 + 2 + 2] cyclotrimerisation reaction of the corresponding alkyne monomers. The preliminary electrochemical behaviour of the new complexes was also evaluated by cyclic voltametry. (C) 2001 Elsevier Science BN. All rights reserved.

引用

页码：84 / 88

页数：5

共 40 条

[1] Synthesis, crystal structures, and second-order nonlinear optical properties of new chiral ferrocenyl materials [J].

Balavoine, GGA ;

Daran, JC ;

Iftime, G ;

Lacroix, PG ;

Manoury, E ;

Delaire, JA ;

Maltey-Fanton, I ;

Nakatani, K ;

Di Bella, S .

ORGANOMETALLICS, 1999, 18 (01) :21-29

[2] Studies of the electronic structure of metallocene-based second-order nonlinear optical dyes [J].

Barlow, S ;

Bunting, HE ;

Ringham, C ;

Green, JC ;

Bublitz, GU ;

Boxer, SG ;

Perry, JW ;

Marder, SR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (15) :3715-3723

[3] Electronic and optical properties of conjugated group 8 metallocene derivatives [J].

Barlow, S ;

Marder, SR .

CHEMICAL COMMUNICATIONS, 2000, (17) :1555-1562

[4] Large quadratic hyperpolarizabilities with donor-acceptor polyenes exhibiting optimum bond length alternation: Correlation between structure and hyperpolarizability [J].

BlanchardDesce, M ;

Alain, V ;

Bedworth, PV ;

Marder, SR ;

Fort, A ;

Runser, C ;

Barzoukas, M ;

Lebus, S ;

Wortmann, R .

CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (07) :1091-1104

[5] STAR-SHAPED TRICARBONYL(CYCLOBUTADIENE)IRON AND CYMANTRENE COMPLEXES - BUILDING-BLOCKS FOR CARBON NETS AND ORGANOMETALLIC CONSTRUCTION SETS [J].

BUNZ, UHF ;

ENKELMANN, V .

ORGANOMETALLICS, 1994, 13 (10) :3823-3833

[6] FINE FEATHERS MAKE FINE BIRDS - THE HECK REACTION IN MODERN GARB [J].

DE MEIJERE, A ;

MEYER, FE .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1994, 33 (23-24) :2379-2411

[7] Switchable mesomorphic materials based on the ferrocene-ferrocenium redox system: Electron-transfer-generated columnar liquid-crystalline phases [J].

Deschenaux, R ;

Schweissguth, M ;

Vilches, MT ;

Levelut, AM ;

Hautot, D ;

Long, GJ ;

Luneau, D .

ORGANOMETALLICS, 1999, 18 (26) :5553-5559

[8] HEXAETHYNYLBENZENE [J].

DIERCKS, R ;

ARMSTRONG, JC ;

BOESE, R ;

VOLLHARDT, KPC .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (03) :268-269

[9] TRIS(BENZOCYCLOBUTADIENO)BENZENE, THE TRIANGULAR [4]PHENYLENE WITH A COMPLETELY BOND-FIXED CYCLOHEXATRIENE RING - COBALT-CATALYZED SYNTHESIS FROM HEXAETHYNYLBENZENE AND THERMAL RING-OPENING TO 1,2-5,6-9,10-TRIBENZO-3,4,7,8,11,12-HEXADEHYDRO[12]-ANNULENE [J].

DIERCKS, R ;

VOLLHARDT, KPC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (11) :3150-3152

[10]

FILLAUT JL, 1994, ANGEW CHEM INT EDIT, V33, P3361

← 1 2 3 4 →