Palladium on carbon encapsulated in POEPOP1500:: A resin-supported catalyst for hydrogenation reactions

被引：27

作者：

Jansson, AM ^{[1
]}

Grotli, M ^{[1
]}

Halkes, KM ^{[1
]}

Meldal, M ^{[1
]}

机构：

[1] Carlsberg Lab, Dept Chem, DK-2500 Copenhagen, Denmark

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 01期

关键词：

D O I：

10.1021/ol016812x

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A new a versatile catalyst for hydrogenation reactions wherein palladium on carbon is encapsulated in POEPOP1500-resin is described. This polymer-supported catalyst has been successfully used in solution phase hydrogenation of a double and a triple bond as well as hydrogenolysis of a benzyl-protecting group. While the activity of the new catalyst is marginally lower than standard 10% Pd/C, it has the advantage of being reused several times without significant loss of reactivity.

引用

页码：27 / 30

页数：4

共 16 条

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