Cyclopalladation of N-N′ donor ligands:: unusual dinuclear complexes and their solution behaviour

被引：13

作者：

Gómez, M ^{[1
]}

Granell, J ^{[1
]}

Martinez, M ^{[1
]}

机构：

[1] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 01期

关键词：

palladacycles; tridentate imines; mass spectrometry; solution behaviour;

D O I：

10.1016/S1387-7003(01)00353-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of new cyclopalladated compounds by reaction between palladium acetate and the potentially tridentate imines 4-ClC6H4CH=N(CH2)(n)NMe2 (n = 2, 3) in acetic acid is described. The experimental data suggest a dinuclear structure for the complexes. with a bridging C-N-N' ligand. H-1 NMR spectra of these complexes in CD3COOD solution, indicate the existence of three different species in equilibrium. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：67 / 70

页数：4

共 15 条

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