A versatile di(8-hydroxyquinoline) building block for supramolecular as well as metallo-supramolecular chemistry

被引:35
作者
Albrecht, M
Blau, O
Wegelius, E
Rissanen, K
机构
[1] Univ Karlsruhe, Inst Organ Chem, D-76131 Karlsruhe, Germany
[2] Univ Jyvaskyla, Dept Chem, SF-40351 Jyvaskyla, Finland
关键词
D O I
10.1039/a902391g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the solid state the di(8-hydroxyquinoline) derivative 2-H-2 forms a hydrogen bonded polymer while with gallium(ru) nitrate a cryptate-type triple-stranded meso-helicate [M subset of {(2)(3)Ga-2}](+) is obtained in the presence of the appropriate alkali metal cations as templates. The templates can have a crucial influence on the self-recognition of the ligands, if the complex formation is performed with ligand mixtures.
引用
收藏
页码:667 / 668
页数:2
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