Catalytic hydrophosphination of styrenes

被引:139
作者
Shulyupin, MO [1 ]
Kazankova, MA [1 ]
Beletskaya, IP [1 ]
机构
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow, Russia
关键词
D O I
10.1021/ol017238s
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] The first example of intermolecular hydrophosphination of styrenes catalyzed by Ni and Pd complexes is described. The reaction of Ph2PH with styrene, 4-vinylpyridine, 2-vinylpyridine, 4-methoxystyrene, 2-methoxystyrene, and 5-vinyl-2-methylpyridine in benzene under Ni[P(OEt)(3)](4) catalysis proceeds with high yield and selectivity to give only anti-Markovnikov product.
引用
收藏
页码:761 / 763
页数:3
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