Catalytic hydrophosphination of styrenes

被引：139

作者：

Shulyupin, MO ^{[1
]}

Kazankova, MA ^{[1
]}

Beletskaya, IP ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow, Russia

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 05期

关键词：

D O I：

10.1021/ol017238s

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The first example of intermolecular hydrophosphination of styrenes catalyzed by Ni and Pd complexes is described. The reaction of Ph2PH with styrene, 4-vinylpyridine, 2-vinylpyridine, 4-methoxystyrene, 2-methoxystyrene, and 5-vinyl-2-methylpyridine in benzene under Ni[P(OEt)(3)](4) catalysis proceeds with high yield and selectivity to give only anti-Markovnikov product.

引用

页码：761 / 763

页数：3

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