Catalytic enantioselective hydrogenolysis of [Cr(CO)3(5,8-dibromonaphthalene)]

被引：47

作者：

Kündig, EP

Chaudhuri, PD

House, D

Bernardinelli, G

机构：

[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva 4, Switzerland

[2] Univ Geneva, Crystallog Lab, CH-1211 Geneva, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 07期

关键词：

asymmetric synthesis; chromium; hydrogenolysis; P ligands; palladium;

D O I：

10.1002/anie.200502688

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Split and run: A study of the asymmetric hydrogenolysis of an aryl-carbon-bromine bond in a naphthalene chromiumtricarbonyl complex shows the use of a new bulky phosphoramidite ligand to yield the product in highly enantiomerically enriched form (see scheme). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：1092 / 1095

页数：4

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