Highly enantioselective hydrovinylation of α-alkyl vinylarenes.: An approach to the construction of all-carbon quaternary stereocenters

被引：96

作者：

Shi, WJ

Zhang, Q

Xie, JH

Zhu, SF

Hou, GH

Zhou, QL ^{[1
]}

机构：

[1] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China

[2] Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 09期

关键词：

D O I：

10.1021/ja057654y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The highly enantioselective hydrovinylation of α-alkyl vinylarenes was realized by using nickel complexes of chiral spiro phosphoramidite ligands. The method provided a new approach to the construction of chiral all-carbon quaternary centers. Copyright © 2006 American Chemical Society.

引用

页码：2780 / 2781

页数：2

共 32 条

[1]

Christoffers J, 2001, ANGEW CHEM INT EDIT, V40, P4591, DOI 10.1002/1521-3773(20011217)40:24<4591::AID-ANIE4591>3.0.CO

[2]

2-V

[3]

Corey EJ, 1998, ANGEW CHEM INT EDIT, V37, P388, DOI 10.1002/(SICI)1521-3773(19980302)37:4<388::AID-ANIE388>3.0.CO

[4]

2-V