Oligomeric Donor Material for High-Efficiency Organic Solar Cells: Breaking Down a Polymer

被引:73
作者
Yuan, Liu [1 ,2 ]
Zhao, Yifan [3 ]
Zhang, Jianqi [1 ]
Zhang, Yajie [1 ]
Zhu, Lingyun [1 ]
Lu, Kun [1 ]
Yan, Wei [3 ]
Wei, Zhixiang [1 ,2 ]
机构
[1] Natl Ctr Nanosci & Technol, Beijing 100190, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Xi An Jiao Tong Univ, Dept Environm Sci & Engn, Xian 710049, Peoples R China
基金
中国国家自然科学基金;
关键词
molecular ordering; oligomers; polymers; phase separation; small molecules; FIELD-EFFECT TRANSISTORS; SMALL-MOLECULE; CHARGE-TRANSPORT; SEMICONDUCTING POLYMERS; CONJUGATED MATERIALS; EXCITON DIFFUSION; HIGH-MOBILITY; PERFORMANCE; BENZODITHIOPHENE; MORPHOLOGY;
D O I
10.1002/adma.201501491
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A comparison study of photovoltaic properties of an oligomer and a polymer based on the same backbone structure is conducted to show that high-efficiency small molecules can be developed from breaking down polymers. The oligomer attains high-efficiency as a result of the high-degree molecular ordering and the excellent intrinsic phase separation with [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM). © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:4229 / 4233
页数:5
相关论文
共 44 条
[1]   Development of Novel Conjugated Donor Polymers for High-Efficiency Bulk-Heterojunction Photovoltaic Devices [J].
Chen, Junwu ;
Cao, Yong .
ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (11) :1709-1718
[2]   Recent Progress in Polymer Solar Cells: Manipulation of Polymer: Fullerene Morphology and the Formation of Efficient Inverted Polymer Solar Cells [J].
Chen, Li-Min ;
Hong, Ziruo ;
Li, Gang ;
Yang, Yang .
ADVANCED MATERIALS, 2009, 21 (14-15) :1434-1449
[3]   Two-dimensional benzodithiophene and benzothiadiazole based solution-processed small molecular organic field-effect transistors & solar cells [J].
Chen, Yanhua ;
Yan, Yan ;
Du, Zhengkun ;
Bao, Xichang ;
Liu, Qian ;
Roy, V. A. L. ;
Sun, Mingliang ;
Yang, Renqiang ;
Lee, Chun Sing .
JOURNAL OF MATERIALS CHEMISTRY C, 2014, 2 (20) :3921-3927
[4]   Low Band-Gap Conjugated Polymers with Strong Interchain Aggregation and Very High Hole Mobility Towards Highly Effi cient Thick- Film Polymer Solar Cells [J].
Chen, Zhenhui ;
Cai, Ping ;
Chen, Junwu ;
Liu, Xuncheng ;
Zhang, Lianjie ;
Lan, Linfeng ;
Peng, Junbiao ;
Ma, Yuguang ;
Cao, Yong .
ADVANCED MATERIALS, 2014, 26 (16) :2586-2591
[5]  
Coffin RC, 2009, NAT CHEM, V1, P657, DOI [10.1038/NCHEM.403, 10.1038/nchem.403]
[6]  
Cornil J, 2001, ADV MATER, V13, P1053, DOI 10.1002/1521-4095(200107)13:14<1053::AID-ADMA1053>3.0.CO
[7]  
2-7
[8]   Charge transport in organic semiconductors [J].
Coropceanu, Veaceslav ;
Cornil, Jerome ;
da Silva Filho, Demetrio A. ;
Olivier, Yoann ;
Silbey, Robert ;
Bredas, Jean-Luc .
CHEMICAL REVIEWS, 2007, 107 (04) :926-952
[9]   Design and Synthesis of Molecular Donors for Solution-Processed High-Efficiency Organic Solar Cells [J].
Coughlin, Jessica E. ;
Henson, Zachary B. ;
Welch, Gregory C. ;
Bazan, Guillermo C. .
ACCOUNTS OF CHEMICAL RESEARCH, 2014, 47 (01) :257-270
[10]   π-Conjugated Polymers for Organic Electronics and Photovoltaic Cell Applications [J].
Facchetti, Antonio .
CHEMISTRY OF MATERIALS, 2011, 23 (03) :733-758