Prochiral selectivity and deuterium kinetic isotope effect in the oxidation of benzyl alcohol catalyzed by chloroperoxidase

被引：11

作者：

Baciocchi, E ^{[1
]}

Lanzalunga, O

Manduchi, L

机构：

[1] Univ La Sapienza, Dipartimento Chim, Rome, Italy

[2] Univ La Sapienza, CNR, Ctr Studio Meccanismo Reaz, Rome, Italy

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a904327f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chloroperoxidase-catalyzed oxidation of benzyl alcohol exhibits a very high prochiral selectivity, involving only the cleavage of the pro-S C-H bond.

引用

页码：1715 / 1716

页数：2

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