共 51 条
A high-mobility electron-transporting polymer for printed transistors
被引:2695
作者:
Yan, He
[1
]
Chen, Zhihua
[1
]
Zheng, Yan
[1
]
Newman, Christopher
[1
]
Quinn, Jordan R.
[1
]
Dotz, Florian
[2
]
Kastler, Marcel
[3
]
Facchetti, Antonio
[1
]
机构:
[1] Polyera Corp, Skokie, IL 60077 USA
[2] BASF Global Res Ctr Singapore, Singapore 112575, Singapore
[3] BASF SE, GKS E B001, D-67056 Ludwigshafen, Germany
来源:
关键词:
FIELD-EFFECT TRANSISTORS;
THIN-FILM TRANSISTORS;
ORGANIC TRANSISTORS;
CHARGE-TRANSPORT;
GATE DIELECTRICS;
DESIGN;
SEMICONDUCTORS;
TRANSITION;
DISPLAYS;
VOLTAGE;
D O I:
10.1038/nature07727
中图分类号:
O [数理科学和化学];
P [天文学、地球科学];
Q [生物科学];
N [自然科学总论];
学科分类号:
07 ;
0710 ;
09 ;
摘要:
Printed electronics is a revolutionary technology aimed at unconventional electronic device manufacture on plastic foils, and will probably rely on polymeric semiconductors for organic thin- film transistor (OTFT) fabrication. In addition to having excellent charge- transport characteristics in ambient conditions, such materials must meet other key requirements, such as chemical stability, large solubility in common solvents, and inexpensive solution and/or low- temperature processing. Furthermore, compatibility of both p- channel (hole- transporting) and n- channel (electron- transporting) semiconductors with a single combination of gate dielectric and contact materials is highly desirable to enable powerful complementary circuit technologies, where p- and n- channel OTFTs operate in concert. Polymeric complementary circuits operating in ambient conditions are currently difficult to realize: although excellent p- channel polymers are widely available, the achievement of high- performance n- channel polymers is more challenging. Here we report a highly soluble (similar to 60 g l(-1)) and printable n- channel polymer exhibiting unprecedented OTFT characteristics ( electron mobilities up to similar to 0.45 - 0.85 cm(2) V-1 s(-1)) under ambient conditions in combination with Au contacts and various polymeric dielectrics. Several top- gate OTFTs on plastic substrates were fabricated with the semiconductor- dielectric layers deposited by spin- coating as well as by gravure, flexographic and inkjet printing, demonstrating great processing versatility. Finally, all- printed polymeric complementary inverters ( with gain 25-65) have been demonstrated.
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页码:679 / U1
页数:9
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