A high-mobility electron-transporting polymer for printed transistors

被引:2695
作者
Yan, He [1 ]
Chen, Zhihua [1 ]
Zheng, Yan [1 ]
Newman, Christopher [1 ]
Quinn, Jordan R. [1 ]
Dotz, Florian [2 ]
Kastler, Marcel [3 ]
Facchetti, Antonio [1 ]
机构
[1] Polyera Corp, Skokie, IL 60077 USA
[2] BASF Global Res Ctr Singapore, Singapore 112575, Singapore
[3] BASF SE, GKS E B001, D-67056 Ludwigshafen, Germany
关键词
FIELD-EFFECT TRANSISTORS; THIN-FILM TRANSISTORS; ORGANIC TRANSISTORS; CHARGE-TRANSPORT; GATE DIELECTRICS; DESIGN; SEMICONDUCTORS; TRANSITION; DISPLAYS; VOLTAGE;
D O I
10.1038/nature07727
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Printed electronics is a revolutionary technology aimed at unconventional electronic device manufacture on plastic foils, and will probably rely on polymeric semiconductors for organic thin- film transistor (OTFT) fabrication. In addition to having excellent charge- transport characteristics in ambient conditions, such materials must meet other key requirements, such as chemical stability, large solubility in common solvents, and inexpensive solution and/or low- temperature processing. Furthermore, compatibility of both p- channel (hole- transporting) and n- channel (electron- transporting) semiconductors with a single combination of gate dielectric and contact materials is highly desirable to enable powerful complementary circuit technologies, where p- and n- channel OTFTs operate in concert. Polymeric complementary circuits operating in ambient conditions are currently difficult to realize: although excellent p- channel polymers are widely available, the achievement of high- performance n- channel polymers is more challenging. Here we report a highly soluble (similar to 60 g l(-1)) and printable n- channel polymer exhibiting unprecedented OTFT characteristics ( electron mobilities up to similar to 0.45 - 0.85 cm(2) V-1 s(-1)) under ambient conditions in combination with Au contacts and various polymeric dielectrics. Several top- gate OTFTs on plastic substrates were fabricated with the semiconductor- dielectric layers deposited by spin- coating as well as by gravure, flexographic and inkjet printing, demonstrating great processing versatility. Finally, all- printed polymeric complementary inverters ( with gain 25-65) have been demonstrated.
引用
收藏
页码:679 / U1
页数:9
相关论文
共 51 条
[1]   n-Type organic field-effect transistors with very high electron mobility based on thiazole oligomers with trifluoromethylphenyl groups [J].
Ando, S ;
Murakami, R ;
Nishida, J ;
Tada, H ;
Inoue, Y ;
Tokito, S ;
Yamashita, Y .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (43) :14996-14997
[2]   High performance n-channel organic field-effect transistors and ring oscillators based on C60 fullerene films [J].
Anthopoulos, Thomas D. ;
Singh, Birendra ;
Marjanovic, Nenad ;
Sariciftci, Niyazi S. ;
Ramil, Alberto Montaigne ;
Sitter, Helmut ;
Colle, Michael ;
de Leeuw, Dago M. .
APPLIED PHYSICS LETTERS, 2006, 89 (21)
[3]   Printable organic and polymeric semiconducting materials and devices [J].
Bao, ZN ;
Rogers, JA ;
Katz, HE .
JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (09) :1895-1904
[4]   Self-assembly, molecular packing, and electron transport in n-type polymer semiconductor nanobelts [J].
Briseno, Alejandro L. ;
Mannsfeld, Stefan C. B. ;
Shamberger, Patrick J. ;
Ohuchi, Fumio S. ;
Bao, Zhenan ;
Jenekhe, Samson A. ;
Xia, Younan .
CHEMISTRY OF MATERIALS, 2008, 20 (14) :4712-4719
[5]   Patterning organic single-crystal transistor arrays [J].
Briseno, Alejandro L. ;
Mannsfeld, Stefan C. B. ;
Ling, Mang M. ;
Liu, Shuhong ;
Tseng, Ricky J. ;
Reese, Colin ;
Roberts, Mark E. ;
Yang, Yang ;
Wudl, Fred ;
Bao, Zhenan .
NATURE, 2006, 444 (7121) :913-917
[6]   Relative importance of polaron activation and disorder on charge transport in high-mobility conjugated polymer field-effect transistors [J].
Chang, Jui-Fen ;
Sirringhaus, Henning ;
Giles, Mark ;
Heeney, Martin ;
McCulloch, Iain .
PHYSICAL REVIEW B, 2007, 76 (20)
[7]   Naphthalenedicarboximide- vs Perylenedicarboximide-Based Copolymers. Synthesis and Semiconducting Properties in Bottom-Gate N-Channel Organic Transistors [J].
Chen, Zhihua ;
Zheng, Yan ;
Yan, He ;
Facchetti, Antonio .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (01) :8-+
[8]   Organic thin film transistors based on N-alkyl perylene diimides:: Charge transport kinetics as a function of gate voltage and temperature [J].
Chesterfield, RJ ;
McKeen, JC ;
Newman, CR ;
Ewbank, PC ;
da Silva, DA ;
Brédas, JL ;
Miller, LL ;
Mann, KR ;
Frisbie, CD .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (50) :19281-19292
[9]   Determination of carrier mobility in phenylamine by time-of-flight, dark-injection, and thin film transistor techniques [J].
Cheung, C. H. ;
Kwok, K. C. ;
Tse, S. C. ;
So, S. K. .
JOURNAL OF APPLIED PHYSICS, 2008, 103 (09)
[10]   High-capacitance ion gel gate dielectrics with faster polarization response times for organic thin film transistors [J].
Cho, Jeong Ho ;
Lee, Jiyoul ;
He, Yiyong ;
Kim, BongSoo ;
Lodge, Timothy P. ;
Frisbie, C. Daniel .
ADVANCED MATERIALS, 2008, 20 (04) :686-+