Theoretical and experimental analysis of N2-H2 stimulated Raman spectra

被引：8

作者：

Gomez, L.

Bermejo, D.

Joubert, P. ^{[1
]}

Bonamy, J.

机构：

[1] Inst Estruct Mat, E-28006 Madrid, Spain

[2] Univ Franche Comte, F-25030 Besancon, France

来源：

MOLECULAR PHYSICS | 2006年 / 104卷 / 12期

关键词：

D O I：

10.1080/00268970600632724

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

The paper reports on a detailed study of the N-2-H-2 collisional line broadening coefficient. High resolution stimulated Raman spectra of nitrogen-hydrogen mixtures have been recorded at liquid nitrogen and room temperatures. Corresponding linewidth calculations have been performed at temperatures between 77 and 500 K using the semiclassical Robert and Bonamy model for J rotational quantum numbers varying between 0 and 11. Comparison between experimental data and calculated results shows good agreement at room temperature using an adjusted value for the kinetic diameter.

引用

收藏

页码：1869 / 1878

页数：10

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