Effects of acidity on the size of polyaniline-poly(sodium 4-styrenesulfonate) composite particles and the stability of corresponding colloids in water

被引：44

作者：

Li, Ligui ^{[1
]}

Ferng, Linhui ^{[2
]}

Wei, Yen ^{[1
]}

Yang, Catherine ^{[3
]}

Ji, Hai-Feng ^{[1
]}

机构：

[1] Drexel Univ, Dept Chem, Philadelphia, PA 19104 USA

[2] Natl Ilan Univ, Coll Bioresources, Ilan City, Taiwan

[3] Rowan Univ, Dept Chem, Glassboro, NJ 08028 USA

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2012年 / 381卷

关键词：

Polyaniline; Poly(sodium 4-styrenesulfonate); PANI; PSS; PANI-PSS nanoparticles; Conductive polymer; CONDUCTING MOLECULAR-COMPLEX; THIN-FILMS; DOPED POLYANILINE; CHEMICAL POLYMERIZATION; ENZYMATIC-SYNTHESIS; THERMAL-STABILITY; POLYMERS; ANILINE; PROCESSIBILITY; NANOPARTICLES;

D O I：

10.1016/j.jcis.2012.05.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The practical application of polyaniline-poly(sodium 4-styrenesulfonate) (PANI-PSS) composite particles has been held back by the low stability of their dispersed state in water. In this work, we present a general oxidation approach to prepare PANI-PSS composite nanoparticles that can form highly stable colloids in water or buffer over a wide range of pH from 1 to 11. We demonstrate that the size of the PANI-PSS composite particles can be controlled by the acidity of precursor solutions. It is hypothesized that the number of negatively charged sites on PSS, which can be affected by the acidity of the precursor solutions, plays an important role in determining the size of the PANI-PSS composite particles and the stability of corresponding colloids in water. (C) 2012 Elsevier Inc. All rights reserved.

引用

页码：11 / 16

页数：6

共 54 条

[1] ELECTROCHEMICALLY INDUCED CHARGE AND MASS-TRANSPORT IN POLYPYRROLE/POLY(STYRENESULFONATE) MOLECULAR COMPOSITES [J].