Cooperative halide, perrhenate anion-sodium cation binding and pertechnetate extraction and transport by a novel tripodal tris(amido benzo-15-crown-5) ligand

被引：179

作者：

Beer, PD

Hopkins, PK

McKinney, JD

机构：

[1] Univ Oxford, Inorgan Chem Lab, Dept Chem, Oxford OX1 3QR, England

[2] BNFL, Preston PR4 0XJ, Lancs, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 13期

关键词：

D O I：

10.1039/a903440d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new tripodal tris(amido benzo-15-crown-5) ligand L-1 cooperatively binds chloride, iodide and perrhenate anions via co-bound crown ether complexed sodium cations and efficiently extracts and transports the pertechnetate anion from simulated aqueous nuclear waste solutions via cooperative ion-pair binding effects.

引用

页码：1253 / 1254

页数：2

共 15 条

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