Preparation of(±)-[1.2-13C2]abscisic acid for use as a stable and pure internal standard

被引：11

作者：

Asami, T ^{[1
]}

Sekimata, K

Wang, JM

Yoneyama, K

Takeuchi, Y

Yoshida, S

机构：

[1] RIKEN, Inst Phys & Chem Res, Plant Funct Lab, Wako, Saitama 3510198, Japan

[2] Utsunomiya Univ, Ctr Res Wild Plants, Utsunomiya, Tochigi 3210185, Japan

来源：

JOURNAL OF CHEMICAL RESEARCH-S | 1999年 / 11期

关键词：

D O I：

10.1039/a904712c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[1,2-C-13(2)]ABA, which is designed as a stable and pure internal standard for GC/MS analysis, is synthesized through the Witting reaction of 1-hydroxy-4-keto-alpha-ionone with carbomethoxymethylenetriphenyl phosphorane prepared from [1,2-C-13(2)]bromoacetic acid followed by saponification of the product methyl [1,2-C-13(2)]ABA.

引用

页码：658 / 659

页数：3

共 4 条

[1]

MILBORROW BV, 1969, CHEM COMMUN, P966

[2] DETERMINATION OF ABSCISIC-ACID IN EUCALYPTUS-HAEMASTOMA LEAVES USING GAS-CHROMATOGRAPHY MASS-SPECTROMETRY AND DEUTERATED INTERNAL STANDARDS [J].

NETTING, AG ;

MILBORROW, BV ;

DUFFIELD, AM .

PHYTOCHEMISTRY, 1982, 21 (02) :385-389

[3] SYNTHESIS OF (RS)-ABSCISIC ACID [J].

ROBERTS, DL ;

HECKMAN, RA ;

HEGE, BP ;

BELLIN, SA .

JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (09) :3566-+

[4]

ZEEVAART JAD, 1988, ANNU REV PLANT PHYS, V39, P439, DOI 10.1146/annurev.pp.39.060188.002255

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