The morphology, structure and electrochemical properties of LiNi1/3Mn1/3Co1/3O2 prepared by electrospun method

被引:26
作者
Ding, Yanhuai [1 ,2 ]
Zhang, Ping [1 ,2 ]
Long, Zhilin [1 ,2 ]
Jiang, Yong [1 ,2 ]
Gao, Deshu [3 ]
机构
[1] Xiangtan Univ, Coll Civil Engn & Mech, Xiangtan 411105, Hunan, Peoples R China
[2] Xiangtan Univ, Inst Fundamental Mech & Mat Engn, Xiangtan 411105, Hunan, Peoples R China
[3] Xiangtan Univ, Coll Chem, Xiangtan 411105, Hunan, Peoples R China
关键词
cathode material; LiNi1/3Mn1/3Co1/3O2; nanofiber; electrospun; electrochemical property;
D O I
10.1016/j.jallcom.2007.08.040
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
LiNi1/3Mn1/3Co1/3O2 nanofibers as cathode materials for lithium ion batteries were prepared from sol-gel precursor by using electrospun method. The morphology of nanofibers mats was investigated by atomic force microscope (AFM). The results show that the diameter of LiNi1/3Mn1/3Co1/3O2 nanofibers was in the range of 100-300 nm and nanofibers retained the original morphology feature of gel fibers after sintering at high temperature. X-ray diffraction (XRD) and charge-discharge experiments were used to characterize its structure and electrochemical properties. The specific capacity of LiNi1/3Mn1/3Co1/3O2 nanofibers reached 162.82 and 135.18 m Ah g(-1) at 0.2 and 2.0 C, respectively. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:340 / 342
页数:3
相关论文
共 16 条
[1]   Fabrication of transparent alumina (Al2O3) nanofibers by electrospinning [J].
Azad, Abdul-Majeed .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2006, 435 :468-473
[2]   An electrospun poly(vinylidene fluoride) nanofibrous membrane and its battery applications [J].
Choi, SW ;
Jo, SM ;
Lee, WS ;
Kim, YR .
ADVANCED MATERIALS, 2003, 15 (23) :2027-2032
[3]   Electrochemical and spectroscopic properties of electrospun PAN-based fibrous polymer electrolytes [J].
Choi, SW ;
Kim, JR ;
Jo, SM ;
Lee, WS ;
Kim, YR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (05) :A989-A995
[4]   Synthesis and electrochemical properties of layered Li[Ni1/3Co1/3Mn1/3]0.96Ti0.04O1.96F0.04 as cathode material for lithium-ion batteries [J].
Ding, Yanhuai ;
Zhang, Ping ;
Gao, Deshu .
JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 456 (1-2) :344-347
[5]   Nanostructured LiCoO2 and LiMn2O4 fibers fabricated by a high frequency electrospinning [J].
Fu, ZW ;
Ma, J ;
Qin, QZ .
SOLID STATE IONICS, 2005, 176 (17-18) :1635-1640
[6]   Structural and electrochemical properties of LiNi1/3Mn1/3Co1/3O2-xFx prepared by solid state reaction [J].
Kageyama, Masaya ;
Li, Decheng ;
Kobayakawa, Koichi ;
Sato, Yuichi ;
Lee, Yun-Sung .
JOURNAL OF POWER SOURCES, 2006, 157 (01) :494-500
[7]   Synthesis and electrochemical properties of Li[Ni1/3Co1/3Mn(1/3-x)Mgx]O2-yFy via coprecipitation [J].
Kim, GH ;
Myung, ST ;
Bang, HJ ;
Prakash, J ;
Sun, YK .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (12) :A477-A480
[8]   Characterization and properties of P(VdF-HFP)-based fibrous polymer electrolyte membrane prepared by electrospinning [J].
Kim, JR ;
Choi, SW ;
Jo, SM ;
Lee, WS ;
Kim, BC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (02) :A295-A300
[9]   Electrospun PVdF-based fibrous polymer electrolytes for lithium ion polymer batteries [J].
Kim, JR ;
Choi, SW ;
Jo, SM ;
Lee, WS ;
Kim, BC .
ELECTROCHIMICA ACTA, 2004, 50 (01) :69-75
[10]   Electrospun mesoporous molecular sieve fibers [J].
Madhugiri, S ;
Zhou, WL ;
Ferraris, JP ;
Balkus, KJ .
MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 63 (1-3) :75-84