Easy preparation of Collman-type reagents: Reaction of [HFe(CO)(4)](-) with tris(dimethylamino)phosphine

被引：9

作者：

Brunet, JJ

Chauvin, R

Neibecker, D

机构：

[1] Lab. de Chim. de Coord. du CNRS, Unité N 8241, Conventions l'Univ. Paul S., 31 077 Toulouse Cedex

来源：

SYNTHETIC COMMUNICATIONS | 1997年 / 27卷 / 08期

关键词：

D O I：

10.1080/00397919708006074

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of tris(dimethylamino)phosphine with MHFe(CO)(4) (M = Na, K) is described. Instead of a CO-substitution at the Fe atom, a formal Me(2)N-substitution occurs at the P atom. Simultaneously, the Collman-type reagent M(2)Fe(CO)(4) is produced in good yield.

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收藏

页码：1433 / 1437

页数：5

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