Formation of two-dimensional supramolecular icelike layer containing (H2O)12 rings

被引:226
作者
Ma, BQ [1 ]
Sun, HL [1 ]
Gao, S [1 ]
机构
[1] Peking Univ, Coll Chem & Mol Engn, PKU HKU Lab Rare Earth Mat & Bioinorgan Chem, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
关键词
D O I
10.1002/anie.200353097
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Water rings: Two novel water chains and layers have been observed in supramolecular solid states. The structures can be interconverted by varying crystallization conditions. The water layer consisting of fused (H 2O)12 rings (see structure, O red, H blue) resembles ice Ih.
引用
收藏
页码:1374 / 1376
页数:3
相关论文
共 28 条
[1]   A well-resolved ice-like (H2O)8 cluster in an organic supramolecular complex [J].
Atwood, JL ;
Barbour, LJ ;
Ness, TJ ;
Raston, CL ;
Raston, PL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (29) :7192-7193
[2]   An intermolecular (H2O)10 cluster in a solid-state supramolecular complex [J].
Barbour, LJ ;
Orr, GW ;
Atwood, JL .
NATURE, 1998, 393 (6686) :671-673
[3]   Inorganic-organic interpenetrating frameworks:: 4,4′-bipyridine N,N′-dioxide as a bridging hydrogen-bond acceptor [J].
Blake, AJ ;
Brett, MT ;
Champness, NR ;
Khlobystov, AN ;
Long, DL ;
Wilson, C ;
Schröder, M .
CHEMICAL COMMUNICATIONS, 2001, (21) :2258-2259
[4]   Synthesis and crystallographic characterization of an octameric water complex, (H2O)8 [J].
Blanton, WB ;
Gordon-Wylie, SW ;
Clark, GR ;
Jordan, KD ;
Wood, JT ;
Geiser, U ;
Collins, TJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (14) :3551-3552
[5]  
Custelcean R, 2000, ANGEW CHEM INT EDIT, V39, P3094, DOI 10.1002/1521-3773(20000901)39:17<3094::AID-ANIE3094>3.0.CO
[6]  
2-P
[7]   Novel water clusters in the crystalline state: structures of a symmetrical, cyclic hexamer and an 'opened-cube' octamer [J].
Doedens, RJ ;
Yohannes, E ;
Khan, MI .
CHEMICAL COMMUNICATIONS, 2002, (01) :62-63
[8]  
Eisenberg K., 1969, STRUCTURE PROPERTIES
[9]   Water clusters in organic molecular crystals [J].
Infantes, L ;
Motherwell, S .
CRYSTENGCOMM, 2002, 4 :454-461
[10]   Two-dimensional water and ice layers: Neutron diffraction studies at 278, 263, and 20 K [J].
Janiak, C ;
Scharmann, TG ;
Mason, SA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (47) :14010-14011