Polymer solar cells with novel fullerene-based acceptor

被引:52
作者
Riedel, I [1 ]
Martin, N
Giacalone, F
Segura, JL
Chirvase, D
Parisi, J
Dyakonov, V
机构
[1] Carl von Ossietzky Univ Oldenburg, Inst Phys, Energy & Semicond Res Lab, D-26111 Oldenburg, Germany
[2] Univ Complutense Madrid, Dept Organ Chem, E-28040 Madrid, Spain
关键词
polymer; photovoltaics;
D O I
10.1016/j.tsf.2003.10.088
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Alternative acceptor materials are possible candidates to improve the optical absorption and/or the open circuit voltage of polymer-fullerene solar cells. We studied a novel fullerene-type acceptor, DPM-12, for application in polymer-fullerene bulk heterojunction photovoltaic devices. Though DPM-12 has the identical redox potentials as methanofullerene PCBM, surprisingly high open circuit voltages in the range V-OC=0.95 V were measured for OC1C10-PPV:DPM-12-based samples. The potential for photovoltaic application was studied by means of photovoltaic characterization of solar cells including current-voltage measurements and external quantum yield spectroscopy. Further studies were carried out by profiling the solar cell parameters vs. temperature and white light intensity. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:43 / 47
页数:5
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