Low-Coordinate Iron(I) and Manganese(I) Dimers: Kinetic Stabilization of an Exceptionally Short Fe?Fe Multiple Bond

被引：77

作者：

Fohlmeister, Lea ^{[1
]}

Liu, Shengsi ^{[2
,3
]}

Schulten, Christian ^{[1
]}

Moubaraki, Boujemaa ^{[1
]}

Stasch, Andreas ^{[1
]}

Cashion, John D. ^{[4
]}

Murray, Keith S. ^{[1
]}

Gagliardi, Laura ^{[2
,3
]}

Jones, Cameron ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia

[2] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

[3] Univ Minnesota, Minnesota Supercomp Inst, Minneapolis, MN 55455 USA

[4] Monash Univ, Sch Phys, Melbourne, Vic 3800, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 33期

基金：

澳大利亚研究理事会;

关键词：

density functional calculations; iron; magnesium; manganese; metal-metal interactions; OXIDATION-STATE METALLACYCLES; METAL-METAL DISTANCES; ELECTRONIC-STRUCTURE; MAGNETIC-PROPERTIES; STABLE COMPOUND; COMPLEXES; CHEMISTRY; REACTIVITY; REDUCTION; ANGSTROM;

D O I：

10.1002/anie.201203711

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Not just any old iron! The reduction of a bulky guanidinato iron(II) bromide complex yields a three-coordinate iron(I) dimer that possesses the shortest Fe-Fe interaction (2.127 Å) reported to date. Magnetic, Mössbauer, and computational studies show the unprecedented compound to contain two high-spin iron(I) centers with significant multiple-bond character. A related dimer containing a rare example of an unsupported, carbonyl-free Mn-Mn bond is also described. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8294 / 8298

页数：5

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