Study of non ideality of various aqueous sodium chloride solutions by vapor pressures measurements and correlation of experimental results by Fitter's method

被引:13
作者
Mokbel, I
Ye, S
Jose, J
Xans, P
机构
[1] UNIV LYON 1,CHIM ANALYT LAB,F-69622 VILLEURBANNE,FRANCE
[2] UNIV PAU & PAYS ADOUR,F-64000 PAU,FRANCE
关键词
sodium chloride; aqueous solution; electrolyte; vapor pressure; Fitter's equation; static device;
D O I
10.1051/jcp/1997940122
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
This article reports experimental vapor pressures of water-NaCl solutions covering the whole miscibility range from 255K to 363K depending on solution. The used apparatus is a static device for pure compounds which has been modified in order to study mixtures. This static apparatus permits to measure vapor pressures from 0.5 Pa to 200 000 Pa. Comparisons between experimental and literature data, experimental and calculated values using Fitter's model indicate a good agreement (relative accuracy < 1% in the whole pressure range).
引用
收藏
页码:122 / 137
页数:16
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