An efficient route to well-defined macrocyclic polymers via "Click" cyclization

被引：629

作者：

Laurent, BA ^{[1
]}

Grayson, SM ^{[1
]}

机构：

[1] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 13期

关键词：

D O I：

10.1021/ja0585836

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polystyrene macrocycles have been prepared from ATRP precursors by modification of the terminal bromide to an azide, followed by "click" cyclization with a pendant alkyne from the initiator. This route offers exceptional control over the size and polydispersity of the macrocyclic polymers, as well as providing tolerance to a number of functional groups. Copyright © 2006 American Chemical Society.

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页码：4238 / 4239

页数：2

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