The absorption spectrum of (C2H2)-C-12 between 12 800 and 18 500 cm(-1) .1. Vibrational assignments

被引:29
作者
Campargue, A [1 ]
Temsamani, MA [1 ]
Herman, M [1 ]
机构
[1] FREE UNIV BRUSSELS,LAB CHIM PHYS MOL,B-1050 BRUSSELS,BELGIUM
关键词
D O I
10.1080/002689797172147
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The absorption spectrum of (C2H2)-C-12 has been recorded at high resolution, between 12800 and 18 500 cm(-1), by Fourier transform spectroscopy and intracavity laser absorption spectroscopy. The observation of 23 new vibrational levels is reported. These new data are gathered with all vibrational levels previously reported in the literature from absorption data, above 12 100 cm(-1). The resulting set of 82 levels is assigned by extrapolating the cluster model developed at lower energies (Abbouti Temsamani, M., and Herman, M., 1995, J. chem. Phys., 102, 6371).
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页码:793 / 805
页数:13
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