Acceleration of organic reactions through aqueous solvent effects

被引：332

作者：

Pirrung, MC ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2006年 / 12卷 / 05期

关键词：

green chemistry; high-pressure reactions; solvent effects; water chemistry;

D O I：

10.1002/chem.200500959

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The parallels between organic reactions conducted with water as the solvent and reactions conducted under high pressure can be understood in light of theories of aqueous solvation and hydrophobic effects. Such parallels provide powerful tools for promoting reactions of nonpolar compounds.

引用

页码：1312 / 1317

页数：6

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