Acceleration of organic reactions through aqueous solvent effects

被引:332
作者
Pirrung, MC [1 ]
机构
[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA
关键词
green chemistry; high-pressure reactions; solvent effects; water chemistry;
D O I
10.1002/chem.200500959
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The parallels between organic reactions conducted with water as the solvent and reactions conducted under high pressure can be understood in light of theories of aqueous solvation and hydrophobic effects. Such parallels provide powerful tools for promoting reactions of nonpolar compounds.
引用
收藏
页码:1312 / 1317
页数:6
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