green chemistry;
high-pressure reactions;
solvent effects;
water chemistry;
D O I:
10.1002/chem.200500959
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
The parallels between organic reactions conducted with water as the solvent and reactions conducted under high pressure can be understood in light of theories of aqueous solvation and hydrophobic effects. Such parallels provide powerful tools for promoting reactions of nonpolar compounds.