Solid polymer electrochemical capacitors using heteropoly acid electrolytes

被引：22

作者：

Lian, Keryn ^{[1
]}

Li, Chang Ming ^{[2
]}

机构：

[1] Univ Toronto, Dept Mat Sci & Engn, Toronto, ON M5S 3E4, Canada

[2] Nanyang Technol Univ, Div Bioengn, Singapore 637457, Singapore

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2009年 / 11卷 / 01期

基金：

加拿大自然科学与工程研究理事会;

关键词：

Electrochemical capacitor; Solid polymer electrolyte; Heteropoly acid; Pseudocapacitor; DOUBLE-LAYER CAPACITORS; MEMBRANES;

D O I：

10.1016/j.elecom.2008.10.016

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

An electrochemical capacitor utilizing a polyvinyl alcohol (PVA) and H4SiW12O40 (SiWA) solid polymer electrolyte was developed. The electrolyte was deposited via precursor solution coating followed by thermal pressing and exhibited an ionic conductivity of 0.01 S/cm. The electrolyte has also shown good stability and cycle life. The performance of the solid polymer electrolyte-based capacitor was characterized using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), and was compared to a similar capacitor with an aqueous electrolyte. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：22 / 24

页数：3

共 18 条

[1]

[Anonymous], 1998, P 8 INT SEM DOUBL LA

[2]

BAI L, 1999, Patent No. 5872698

[3] Fabrication and properties of hybrid membranes based on salts of heteropolyacid, zirconium phosphate and polyvinyl alcohol [J].