Vicarious nucleophilic substitution of hydrogen in nitrophenyl toluenesulfonates

被引：12

作者：

Makosza, M

Ziobrowski, T

Serebriakov, M

Kwast, A

机构：

[1] Institute of Organic Chemistry, Polish Academy of Sciences, PL 01-224 Warsaw

[2] Higher Chemical College, Russian Academy of Sciences, Moscow

来源：

TETRAHEDRON | 1997年 / 53卷 / 13期

关键词：

D O I：

10.1016/S0040-4020(97)00143-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Toluenesulfonates of nitrophenols react with carbanions possessing leaving groups giving products of the vicarious nucleophilic substitution of hydrogen. The yields and orientation depend on the reaction conditions and the structure: of the reagents. The products obtained can be easily hydrolyzed to the corresponding phenols or - in certain cases - to hydroxynitrobenzaldehydes. (C) 1997 Elsevier Science Ltd.

引用

页码：4739 / 4750

页数：12

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