Iodination of nitroarenes by a superactive reagent based on iodine chloride

被引：9

作者：

Chaikovskii, VK ^{[1
]}

Kharlova, TS ^{[1
]}

Filimonov, VD ^{[1
]}

机构：

[1] Tomsk Polytech Univ, Dept Organ Chem, Tomsk 634004, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 07期

基金：

俄罗斯基础研究基金会;

关键词：

iodination; iodine chloride; electrophilic iodine; nitroarenes;

D O I：

10.1007/BF02495292

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Iodine chloride reacts with Ag(2)SO(4) in H(2)SO(4) to give a new superelectrophilic reagent capable of iodinating nitrobenzene, halogenated nitrobenzenes, nitrotoluenes, and aromatic compounds with two nitro groups in the ring. Mononitroarenes are easily iodinated at 0-20 degrees C, while dinitroarenes require heating to 100-170 degrees C.

引用

页码：1291 / 1294

页数：4

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