Syntheses and single-crystal X-ray structures of [(ButNP)(2)(ButN)(2)]MCl2 (M=Zr, Hf): the first transition-metal bis(alkylamido)cyclodiphosphazane complexes

被引:46
作者
Grocholl, L
Stahl, L
Staples, RJ
机构
[1] UNIV N DAKOTA,DEPT CHEM,GRAND FORKS,ND 58202
[2] HARVARD UNIV,DEPT CHEM & BIOL CHEM,CAMBRIDGE,MA 02138
关键词
D O I
10.1039/a702606d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The interaction of [((BuNP)-N-t){(BuNLi)-N-t(thf)}(2)] with ZrCl4 and HfCl4 produces the remarkably stable monomeric [((BuNP)-N-t)2((BuN)-N-t)(2)]MCl2 (M = Zr, Hf) complexes.
引用
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页码:1465 / 1466
页数:2
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