Artificial photosynthesis in lamellar assemblies of metal poly(pyridyl) complexes and metalloporphyrins

被引：40

作者：

Kaschak, DM ^{[1
]}

Johnson, SA ^{[1
]}

Waraksa, CC ^{[1
]}

Pogue, J ^{[1
]}

Mallouk, TE ^{[1
]}

机构：

[1] Penn State Univ, Dept Chem, University Pk, PA 16802 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 1999年 / 185-6卷

关键词：

photochemistry; electron transfer; energy transfer; supramolecular chemistry; self-assembly;

D O I：

10.1016/S0010-8545(99)00025-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Multilayer films composed of inorganic colloids (alpha-zirconium phosphate or HTiNbO5) and organic polycations can be grown in almost any desired sequence on surfaces by electrostatic self-assembly. Control of the edge chemistry of the anionic sheets is essential to the preparation of well organized monolayers and multilayers. Examples;are given of layer sequences that incorporate electron donors and accepters, which undergo photoinduced electron transfer reactions across inorganic spacer layers, similar stacking sequences can be used to couple light harvesting assemblies, containing energy donors and acceptors, to electron donor-acceptor dyads. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：403 / 416

页数：14

共 41 条

[1] SYNTHESES, CRYSTALLINE-STRUCTURE, AND ION-EXCHANGE PROPERTIES OF INSOLUBLE ACID SALTS OF TETRAVALENT METALS AND THEIR SALT FORMS
ALBERTI, G
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1978, 11 (04) : 163 - 170
[2] Designing dendrimers based on transition metal complexes. Light-harvesting properties and predetermined redox patterns
Balzani, V
Campagna, S
Denti, G
Juris, A
Serroni, S
Venturi, M
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (01) : 26 - 34
[3] Photocurrent generation in metal bisphosphonate multilayer thin films
Byrd, H
Suponeva, EP
Bocarsly, AB
Thompson, ME
[J]. NATURE, 1996, 380 (6575) : 610 - 612
[4] LAYERED METAL PHOSPHATES AND PHOSPHONATES - FROM CRYSTALS TO MONOLAYERS
CAO, G
HONG, HG
MALLOUK, TE
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (09) : 420 - 427
[5] Fuzzy nanoassemblies: Toward layered polymeric multicomposites
Decher, G
[J]. SCIENCE, 1997, 277 (5330) : 1232 - 1237
[6] PHOTOELECTRON TRANSFER FROM TRIS(2,2'-BIPYRIDINE)RUTHENIUM(II) TO METHYLVIOLOGEN IN ZEOLITE CAGES - A RESONANCE RAMAN-SPECTROSCOPIC STUDY
DUTTA, PK
INCAVO, JA
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (17) : 4443 - 4446
[7] INTRAZEOLITIC PHOTOINDUCED REDOX REACTIONS BETWEEN RU(BPY)32+ AND METHYLVIOLOGEN
DUTTA, PK
TURBEVILLE, W
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (23) : 9410 - 9416
[8] A "mix and match" ionic-covalent strategy for self-assembly of inorganic multilayer films
Fang, MM
Kaschak, DM
Sutorik, AC
Mallouk, TE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (50) : 12184 - 12191
[9] FAULKNER LR, 1982, CHEM ENERGY PRODUCTI, P99
[10] PREPARATIVE-SCALE SEPARATION OF ENANTIOMERS USING INTERCALATED ALPHA-ZIRCONIUM PHOSPHATE
GARCIA, ME
NAFFIN, JL
DONG, NL
MALLOUK, TE
[J]. CHEMISTRY OF MATERIALS, 1995, 7 (10) : 1968 - 1973

← 1 2 3 4 5 →