Radical reduction of aromatic azides to amines with tributylgermanium hydride

被引：25

作者：

Benati, L ^{[1
]}

Bencivenni, G ^{[1
]}

Leardini, R ^{[1
]}

Minozzi, M ^{[1
]}

Nanni, D ^{[1
]}

Scialpi, R ^{[1
]}

Spagnolo, P ^{[1
]}

Zanardi, G ^{[1
]}

机构：

[1] Univ Bologna, Dipartimento Chim Organ A Mangini, I-40136 Bologna, Italy

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 01期

关键词：

D O I：

10.1021/jo0521697

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aromatic azides are inert toward tributylgermanium hydride under thermal conditions in the absence and in the presence of a radical initiator but in the presence of catalytic amounts of benzenethiol undergo fast reaction, yielding reduced anilines and 2-germylated derivatives in high overall yields.

引用

页码：434 / 437

页数：4

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