Layered metal organosulfides:: hydrothermal synthesis, structure and magnetic behaviour of the spin-canted magnet Co(1,2-(O2C)(S)C6H4)

被引：99

作者：

Cave, D

Gascon, JM

Bond, AD

Teat, SJ

Wood, PT

机构：

[1] Univ Cambridge, Chem Lab, Cambridge CB2 1EW, England

[2] CLRC, Daresbury Lab, Warrington WA4 4AD, Cheshire, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 10期

关键词：

D O I：

10.1039/b111339a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of cobalt(II) salts with the thiosalicylate dianion under hydrothermal conditions yields green lamellar Co((O2C)(S)C6H4) which displays canted antiferromagnetism.

引用

页码：1050 / 1051

页数：2

共 19 条

[1] TELLURIDE ALKYLATION AND FORMATION OF NOVEL METAL-CARBONYL POLYTELLURIDE CLUSTERS IN SUPERHEATED ALCOHOLS - ISOLATION OF THE COMPLEXES [M(4)(TE-2)(2)(TE)(2)(TEME)(2)(CO)(8)](2-) (M=FE, RU) [J].

DAS, BK ;

KANATZIDIS, MG .

INORGANIC CHEMISTRY, 1995, 34 (05) :1011-1012

[2] EXPERIMENTS ON SIMPLE MAGNETIC MODEL SYSTEMS [J].

DEJONGH, LJ ;

MIEDEMA, AR .

ADVANCES IN PHYSICS, 1974, 23 (01) :1-260

[3] Synthesis and characterization of Co3(O2CCH2CH2PO3)2•6H2O, a metal carboxylate-phosphonate with a framework structure [J].

Distler, A ;

Sevov, SC .

CHEMICAL COMMUNICATIONS, 1998, (09) :959-960

[4] Unprecedented stabilization of cobalt(II) in a tetrahedral S2O2 environment:: The use of a redox-noninnocent ligand [J].

Duran, N ;

Clegg, W ;

Cucurull-Sánchez, L ;

Coxall, RA ;

Jiménez, HR ;

Moratal, JM ;

Lloret, F ;

González-Duarte, P .

INORGANIC CHEMISTRY, 2000, 39 (21) :4821-4832

[5] COORDINATION-COMPLEXES WITH INFINITE LATTICE STRUCTURES - SOLVOTHERMAL SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF K(2)M[NC5H3(CO2)(2)-2,3](2) (M=MN, ZN) [J].

GUTSCHKE, SOH ;

SLAWIN, AMZ ;

WOOD, PT .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (21) :2197-2198

[6]

Gutschke SOH, 2001, ANGEW CHEM INT EDIT, V40, P1920, DOI 10.1002/1521-3773(20010518)40:10<1920::AID-ANIE1920>3.0.CO

[7]

2-2

[8]

HAGMAN D, 1999, ANGEW CHEM INT EDIT, V38, P3165

[9]

Hanko JA, 1998, ANGEW CHEM INT EDIT, V37, P342, DOI 10.1002/(SICI)1521-3773(19980216)37:3<342::AID-ANIE342>3.0.CO

[10]

2-P

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