Studies on the cyclomercuration of 1,1′- bis [(arylimino)phenylmethyl] ferrocenes

被引：8

作者：

Cui, XL

Wu, YJ ^{[1
]}

Zou, DP

He, CH

Chai, JJ

机构：

[1] Zhengzhou Univ, Dept Chem, Key Lab Appl Chem Henan Prov, Zhengzhou 450052, Peoples R China

[2] Chinese Acad Med Sci, Natl Res Ctr Anal Drugs & Metabolites, Beijing 100050, Peoples R China

来源：

POLYHEDRON | 1999年 / 18卷 / 07期

基金：

美国国家科学基金会;

关键词：

bisferrocenylimine; mercury; crystal structure;

D O I：

10.1016/S0277-5387(98)00388-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

The reaction of bisferrocenylimines with mercuric acetate and subsequent treatment with LiCl lead to formation of mono (9) and double (10) cyclomercurated derivatives. The H-1 NMR and Hg-199 NMR spectra of the double cyclomercurated bisferrocenylimines show that compounds 10 exist as two isomers (meso and dl). The individual stereoisomers were isolated successfully by crystal picking. The structures of these new compounds have been confirmed by elemental analysis, IR and H-1 NMR spectroscopies, and further by X-ray crystal structure determination of meso [{HgCl(eta(5)-C5H3CPh=NAr)}(2)Fe] (Ar=m-CH3C6H4). (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：1023 / 1027

页数：5

共 10 条

[1]

VAN DER WAALS VOLUMES + RADII [J].