Evidence that gold(III) porphyrins are not electrochemically inert:: facile generation of gold(II) 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)porphyrin

被引：49

作者：

Kadish, KM

Wenbo, E

Ou, ZP

Shao, JG

Sintic, PJ

Ohkubo, K

Fukuzumi, S

Crossley, MJ

机构：

[1] Univ Houston, Dept Chem, Houston, TX 77204 USA

[2] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

[3] Osaka Univ, JST,CREST, Grad Sch Engn, Dept Mat & Life Sci, Suita, Osaka 5650871, Japan

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 04期

关键词：

D O I：

10.1039/b109795d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Gold(III) porphyrin 1 is shown to undergo reduction at the central metal ion to give the first known gold(II) porphyrin overturning the long held assumption that reduction of such complexes only occurs at the macrocycle.

引用

页码：356 / 357

页数：2

共 11 条

[1] REDOX CHEMISTRY OF GOLD(III) PORPHYRINS IN WATER [J].

ABOUGAMRA, Z ;

HARRIMAN, A ;

NETA, P .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1986, 82 :2337-2350

[2] PORPHYRINS .38. REDOX POTENTIALS, CHARGE-TRANSFER TRANSITIONS, AND EMISSION OF COPPER, SILVER, AND GOLD COMPLEXES [J].

ANTIPAS, A ;

DOLPHIN, D ;

GOUTERMAN, M ;

JOHNSON, EC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (24) :7705-7709

[3] CHARGE-TRANSFER ACROSS OBLIQUE BISPORPHYRINS - 2-CENTER PHOTOACTIVE MOLECULES [J].

BRUN, AM ;

HARRIMAN, A ;

HEITZ, V ;

SAUVAGE, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (23) :8657-8663

[4]

CROSSLEY MJ, UNPUB

[5] A Zn(II) porphyrin-Ir(III) bis-terpyridine-Au(III) porphyrin triad with a charge-separated state in the microsecond range [J].

Flamigni, L ;

Dixon, IM ;

Collin, JP ;

Sauvage, JP .

CHEMICAL COMMUNICATIONS, 2000, (24) :2479-2480

[6] GENERATION OF AU2+ IONS IN THE SOLID-STATE OR IN FLUOROSULFURIC ACID-SOLUTION AND THEIR IDENTIFICATION BY ESR [J].

HERRING, FG ;

HWANG, G ;

LEE, KC ;

MISTRY, F ;

PHILLIPS, PS ;

WILLNER, H ;

AUBKE, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (04) :1271-1277

[7] GOLD PORPHYRIN COMPLEXES - EVIDENCE FOR ELECTROCHEMICALLY INERT GOLD(III) [J].

JAMIN, ME ;

IWAMOTO, RT .

INORGANICA CHIMICA ACTA, 1978, 27 (01) :135-143

[8] Bridge-dependent electron transfer in porphyrin-based donor-bridge-acceptor systems [J].

Kilså, K ;

Kajanus, J ;

Macpherson, AN ;

Mårtensson, J ;

Albinsson, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (13) :3069-3080

[9] PHTHALOCYANINE OF GOLD [J].

MACCRAGH, A ;

KOSKI, WS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (11) :2496-&

[10]

Sanders J.K.M., 2000, The Porphyrin Handbook, VVolume 3, P1

← 1 2 →