Very stable palladium(II)-(N-N) catalysts for the synthesis of high-molecular-weight CO/styrene polyketones

被引：49

作者：

Milani, B

Scarel, A

Mestroni, G

Gladiali, S

Taras, R

Carfagna, C

Mosca, L

机构：

[1] Univ Trieste, Dipartimento Sci Chim, I-34127 Trieste, Italy

[2] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy

[3] Univ Urbino, Ist Sci Chim, I-61029 Urbino, Italy

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 07期

关键词：

D O I：

10.1021/om011020s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A dicationic (N-N) bis-chelated Pd(II) complex containing the 3-alkyl-substituted 1, 10-phenanthroline 1 as the unique ligand provides exceptionally high productivities in CO/styrene copolymerization, giving a polymer of unprecedentedly high molecular weight.

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页码：1323 / 1325

页数：3

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