Stereochemical anomaly in the thermal conversion of 7,8-dioxy-7-alkenylbenzocyclobutenes to dihydronaphthalenes

被引：24

作者：

Hamura, T

Miyamoto, M

Imura, K

Matsumoto, T

Suzuki, K ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan

[2] CREST, Japan Sci & Technol Corp, Meguro Ku, Tokyo 1528551, Japan

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 10期

关键词：

D O I：

10.1021/ol025726+

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The stereochemistry of the thermal conversion of alkenylbenzocyclobutenol into dihydronaphthalene was studied. Experiments on the substrates IV, in which two oxy functions are cis, often resulted in the formation of abnormal products in view of the orbital consideration.

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收藏

页码：1675 / 1678

页数：4

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