The preparation and structures of hydrogen ordered phases of ice

被引：215

作者：

Salzmann, CG

Radaelli, PG

Hallbrucker, A

Mayer, E

Finney, JL

机构：

[1] Univ Innsbruck, Inst Gen Inorgan & Theoret Chem, A-6020 Innsbruck, Austria

[2] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England

[3] CCLRC, Rutherford Appleton Lab, ISIS Facil, Didcot OX11 0QX, Oxon, England

[4] UCL, Dept Phys & Astron, London WC1E 6BT, England

来源：

SCIENCE | 2006年 / 311卷 / 5768期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1126/science.1123896

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Two hydrogen ordered phases of ice were prepared by cooling the hydrogen disordered ices V and XII under pressure. Previous attempts to unlock the geometrical frustration in hydrogen-bonded structures have focused on doping with potassium hydroxide and have had success in partially increasing the hydrogen ordering in hexagonal ice I (ice Ih). By doping ices V and XII with hydrochloric acid, we have prepared ice XIII and ice XIV, and we analyzed their structures by powder neutron diffraction. The use of hydrogen chloride to release geometrical frustration opens up the possibility of completing the phase diagram of ice.

引用

页码：1758 / 1761

页数：4

共 27 条

[1] A theory of water and ionic solution, with particular reference to hydrogen and hydroxyl ions [J].