First example of thiolate-bridged square-pyramidal and octahedral nickel(II) ions: [Ni-2(L(SO))(NCS)(2)(dmf)]

被引：39

作者：

Brooker, S

Croucher, PD

机构：

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 05期

关键词：

D O I：

10.1039/a607833h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A structure determination reveals that [Ni-2(L(SO))(NCS)(2)(dmf)] 2 is one of the best structural models to date for the active site of [Ni,Fe] hydrogenases: it also contains the first example of a high-spin thiolate-bound square-pyramidal nickel(II) ion.

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页码：459 / 460

页数：2

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