A versatile metal-organic framework for carbon dioxide capture and cooperative catalysis

被引：232

作者：

Park, Jinhee ^{[1
]}

Li, Jian-Rong ^{[1
]}

Chen, Ying-Pin ^{[1
]}

Yu, Jiamei ^{[2
]}

Yakovenko, Andrey A. ^{[1
]}

Wang, Zhiyong U. ^{[1
]}

Sun, Lin-Bing ^{[1
]}

Balbuena, Perla B. ^{[2
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

[2] Texas A&M Univ, Artie McFerrin Dept Chem Engn, College Stn, TX 77842 USA

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 80期

基金：

美国国家科学基金会;

关键词：

HETEROGENEOUS CATALYSIS; HYDROGEN ADSORPTION; STORAGE; FUNCTIONALIZATION; METHANE; DESIGN; LIGAND; UNITS; SIZE; MOFS;

D O I：

10.1039/c2cc34622b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A multi-functional MOF PCN-124 was constructed from Cu paddlewheel motifs and a judiciously designed novel ligand bearing carboxylate, pyridine, and amide groups. PCN-124 exhibits selective adsorption of CO2 over CH4 and excellent catalytic activity in a tandem one-pot deacetalization-Knoevenagel condensation reaction as a cooperative catalyst.

引用

收藏

页码：9995 / 9997

页数：3

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